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HTML stands for "HyperText Markup Language". It is the primary technology behind every websites online. HTML helps to display the informations on screens in a human readable form. You must learn HTML if you wanted to learn web development or if you wants to create your own website!
Java is a high level Object Oriented Programming Language. You can build virtually any type of application or programs with Java. It has a rich libraries of APIs to create rich UI applications. It is also the main language behind the popular Android Apps Development. Java is also easy to learn and understand if you focus on what you are doing.